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The reaction of C(NMe 2 ) 4  (1) with M(CO) 6  (M = Cr, W) in THF solution leads to the anionic carbamoyl complexes [C(NMe 2 ) 3 ][(CO) 5 MC(O)NMe 2 ] (2a, M = Cr; 2c M = W). In the case of M = Mo the resulting complex 2b is not obtained; instead, the salts [C(NMe 2 ) 3 ]2[Mo 2 (CO) 10 ] (3) and [C(NMe 2 ) 3 ][(CO) 4 Mo(O 2 CNMe 2 )] (4) are isolated. The crystal structures of 2a, 3, and 4 are presented. In the salt-like compounds no interatomic contacts between anion and cation exist, and the cations are disordered. The structure of 4 shows two independent molecules. The compounds were further characterized by IR and NMR spectroscopy.

zeitschrift für naturforschung b

Reaktionen von C(NMe 2 ) 4  mit Carbonylverbindungen der 6. Gruppe. Kristallstrukturen von [C(NMe 2 ) 3 ][(CO) 5 CrC(O)NMe 2 ], [C(NMe 2 ) 3 ] 2 [Mo 2 (CO) 10 ] und [C(NMe 2 ) 3 ][(CO) 4 Mo(O 2 CNMe 2 )] / Reactions of C(NMe 2 ,) 4  with Group 6 Carbonyl Compounds. Crystal Structures of [C(NMe 2  ) 3  ][(CO) 5  CrC(O)NMe 2 ], [C(NMe 2 ) 3 ] 2 [Mo 2 (CO) 10 ] and [C(NMe 2 ) 3 ][(CO) 4  Mo(O 2 CNMe 2 )]