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[NMe 4 ] 2  [As 4 O 2 Cl 10 ] · 2 CH 3 CN was recovered by the reaction of [NMe 4 ][N 3 ] with AsCl 3  in CH 3 CN under aerobic conditions. This compound was also obtained directly by the reaction of AsCl 3 , AS 2 O 3  and [NMe 4 ][Cl] in acetonitrile. The structure was determined by X-ray diffraction. [NMe 4 ] 2  [As 4 O 2 Cl 10 ] · 2 CH 3 CN crystallizes in theoorthorhombic space group Fmmm with a = 11.4144(8), b = 14.732(1) and c = 19.803(2) Å, with 4 formula units per unit cell. The frequencies obtained by Raman and infrared spectroscopy were assigned to the normal modes of the [As 4 O 2 Cl 10 ] 2-  anion in comparison with computational results. The bonding situation in the [As 4 O 2 Cl 10 ] 2-  anion was elucidated on the basis of an NBO analysis on the crystallographic data.

Synthesis, Characterization, Crystal Structure and hybrid DFT Computation of the Chlorooxoarsenate(III), [NMe 4 ] 2 [As 4 O 2 Cl 10 ]·2 CH 3 CN