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The chloro bridged complexes [(2-phenylpyridine-C,N) 2 RhCl] 2  and [(benzo[h]chinoline-C,N) 2 RhCl] 2  react with the anions of alanine, valine and phenylalanine to give the chiral octahedral N,O-chelates L 2 Rh(α-aminocarboxylate) (1 -5) as mixtures of two diastereoisomers. The complex (benzo[h]chinoline-C,N) 2 Rh[(S)-NH 2 CH(CH 3 )CO 2 -N,0] was characterized by X-ray diffraction. Its crystals contain two diastereoisomers in the unit cell.

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Metallkomplexe mit biologisch wichtigen Liganden, CXXXIII [1], a-Aminocarboxylat-Chelate von cyclometallierten Rhodium-Komplexen Metal Complexes of Biologically Important Ligands, CXXXIII [1]. α-Aminocarboxylate Chelates of Cyclometalated Rhodium -Komplexes