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The bis(phosphanyl)ylides Ph 3 PC(PPh 2 ) 2 , Ph 3 PC(PPhCl) 2  (3) and Ph 3 PC(PCl 2 ) 2  have analogous molecular structures. Details reflect the different charge transfer from the ylide center to the phosphanyl substituents. Chlorination destroys the chirality of 3. Reduction leads to the diphosphane 8 and the 1,2,4,5-tetraphosphinane 9 which are also included in the structural comparison.

zeitschrift für naturforschung b

Reduktion eines Bis(chlorphenylphosphanyl)methylids zum entsprechenden Diphosphan und Tetraphosphinan Reduction of a Bis(chlorophenylphosphanyl)methylide to the Corresponding Diphosphane and Tetraphosphinane