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The lithium hydridosilylamides Me 2 (H)SiN(Li)R (1: R = CMe 3 , 2: R = SiMe 3 ) were allowed to react either with the non-enolizable carbonyl compounds CH 2 =C(Me)CHO, PhCHO and Ph 2 CO followed by trapping with chlorotrimethylsilane (A), or with mixtures of these carbonyl compounds and chlorotrimethylsilane (B). In the second case the course of the reactions is determined by the carbonyl compound. The composition of the reaction mixtures is nearly the same according to A and B.

zeitschrift für naturforschung b

Reaktionen von Lithiumhydridosilylamiden mit Carbonylverbindungen und Gemischen von Carbonylverbindungen und Chlortrimethylsilan / Reactions of Lithium Hydridosilylamides with Carbonyl Compounds and Mixtures of Carbonyl Compounds and Chlorotrimethylsilane