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Single crystals of Ag 2  SrMnV 2 O 8  have been prepared by reactions of metallic silver and a mixture of SrCO 3 , MnCO 3  · H 2 O and V 2 O 5 . X-Ray investigations showed monoclinic symmetry, space group C 6  2h  -C2/c, a = 9.7022(9), b = 5.5882(5), c = 13.894(1), β = 90.41(1)°, Z = 4. The crystal structure is isotypic to Na 2 BaCuV 2 O 8  and includes VO 4  tetrahedra, MnO 6  octahedra as well as irregular AgO 8  and SrO 10  polyhedra. Ag 2 SrMnV 2 O 8  is characterized by a [MnV 2 O 8 ] network incorporating Ag +  and Sr 2+  or a [Ag 2 V 2 8] frame incorporating Mn 2+  and Sr 2+  ions. Ag +  is able to replace an alkali ion in the cationic part of the crystal structure.

Ag + als Substituent eines Alkalimetalls in Ag 2 SrMnV 2 O 8 / Ag + As Substituent Of An Alkaline Metal In Ag 2 SrMnV 2 O 8