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Single crystals of LaTi(Ti 0.25 Te 0.75 )O 6  have been prepared by solid state reactions. X-ray investigations led to trigonal symmetry, space group C 3  1 -P3 , a = 5.141(10), c = 5.218(10) Å, Z = 1. The compound is characterized by a predominantly ordered distribution of Ti 4+  and Te 6+ . Typical features of the crystal structure are staggered layers containing edge connected TiO 6  and (Ti,Te)O 6  octahedra. The layers are connected by La 3+  ions receiving an octahedral coordination by the surrounding oxygen ions. The relationships to the PbSb 2 O 6  type and the recently described compound Sr(MnTe)O 6  are discussed.

zeitschrift für naturforschung b

Synthese und Kristallstruktur des Lanthan-Titanat-Tellurats LaTi(Ti 0,25 Te 0,75 )O 6  und seine Verwandtschaft mit PbSb 2 O 6  und Sr(MnTe)O 6 /Synthesis and Crystal Structure of the Lanthanum Titanate Tellurate LaTi(Ti 0.25 Te 0.75 )O 6  and its Relationship to PbSb 2 O 6  and Sr(MnTe)O 6