English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The mono-cyclopentadienyl metal complexes CpZrCl 3 (dme) and CpHfCl 3 (dme) react with acetone oxime in the presence of triethylamine to form the isotypic dinuclear complexes [CpMCl 2 ] 2 (μ-ONCMe 2 ) 2 (μ-HONCMe 2 ) (1: M = Zr; 2: M = Hf). 1 and 2 contain two oximato bridges and one oxime bridge. In the presence of water the reaction gives, with partial hydrolysis, the cyclic trinuclear compounds [CpZrCl] 3 (μ 3 -O)(μ 3 -OH)(μ-ONCMe 2 )3·½Me 2 CNOH (3) and [CpHfCl] 3 (μ 3 -O)(μ 3 -Cl)(μ-ONCMe 2 ) 3 ·CH 2 Cl 2  (4). In 1 to 4 the bridging oximato groups are side-on bonded via O and N to one metal atom and via (only) O to the other metal atom. The metal atoms of 1 to 4 exhibit an 18-electron configuration.

Mehrkernige CpZr(IV)-und CpHf(IV)-Komplexe mit Oximatobrücken / Polynuclear CpZr(IV) and CpHf(IV) Complexes with Oximato Bridges