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The dinuclear metallacycle of [Cp′ 2 Ti(μ-S 2 ) 2 TiCp′ 2 .] reacts with phosgene or thiophosgene to give [(Cp′ 2 CITi) 2 S 3 ] which has been characterized by  1 H and  13 C NMR spectra as well as by an X-ray structure analysis. The trisulfido complex contains a helical TiSSSTi unit and may serve as an S 3  transfer reagent in reactions with SCl-functional compounds

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Synthesis and Structure of Bis[di(methylcyclopentadienyl)chloro-titanium]trisulfide [(Cp′ 2 ClTi) 2 S 3 ] - a Reagent for Trisulfide Ligand Transfer Reactions [1]