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The rac-lipoato (lip - ) complexes [Zn(lip) 2 (H 2 O) 2 ] (1) and [Cd(lip) 2 (H 2 O) 2 ] (2) were obtained in good yields from solutions of sodium lipoate and the respective metal nitrate in methanol/water. 1 and 2 form pale yellow, moderately light-sensitive crystals.

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Coordination Chemistry of Lipoic Acid and Related Compounds, Part 1 Syntheses and Crystal Structures of the UV- and Light-Sensitive Lipoato Complexes [M(lip) 2 (H 2 O) 2 ] (M = Zn, Cd)