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New compounds of the composition BaPdLn 2 O 5  (Ln = Eu, Gd, Dy, Ho) have been prepared by crystallization from flux. They crystallize isotypic to BaPtLn 2 O 5 , space group D 5  4h -P4/ mbm. Eu: a = 6.6359(6), c = 5.885(3) Å ; Gd: a = 6.608(3), c = 5.873(3) Å ; Dy: a = 6.5431(7), c = 5.8574(8) Å ; Ho: a = 6.522(4), c = 5.855(5) A , Z = 2. The crystal structure is characterized by isolated planar PdO 4  polygons incorporated into a framework of edge-and corner-sharing doubly capped BaO 8  cubes and edge-and face-sharing LnO 6  prisms.

zeitschrift für naturforschung b

Weitere Verbindungen mit isolierten quadratischen PdO 4 -Polygonen: BaPdLn 2 O 5  (Ln=Eu, Gd, Dy, Ho) / Compounds Containing Isolated Square Planar PdO 4  Polygons: BaPdLn 2 O 5  (Ln=Eu, Gd, Dy, Ho)