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Chiral tripod-ligands of the type 5 are easily accessible in four steps starting from the dibromide 1. The cleavage of the oxetane 4 b by LiPPh 2  yielding the tripod-ligand 5 can be modified enantioselectively by the addition of (-)-sparteine.

zeitschrift für naturforschung b

Der kürzeste Weg zu C 1 -symmetrischen, chiralen tripod-Liganden mit Neopentan-Grundgerüst / The Shortest Way to C 1 -Symmetrical, Chiral Tripod Ligands with Neopentane Backbone