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Organo-substituted 1,3,5-hexahydrotriazine complexes of the type (RNCH 2 ) 3 Mo(CO) 3  (R = CH 3 , i - C 3 H 7  and CH 2 C 6 H 5 ) are obtained by ligand displacement from η 6 -C 7 H 8 Mo(CO) 3  in high yields. These products have been characterized by  1 H,  13 C,  95 Mo NMR, IR as well as mass spectroscopy and contain an electron-rich Mo(C O) 3  center bonded to the 1,3,5-hexahydrotriazine 6e donor via three Mo -N bonds. Oxidation of the Mo 0  complex 1,3,5-(CH 3 NCH 2 ) 3 Mo(CO) 3  with H 2 O 2  under carefully controlled conditions allows isolation of 1,3,5-(CH 3 NCH 2 ) 3 MoO 3  containing a Mo VI  center. Chemical and spectroscopic properties of these complexes are compared with those of related Mo complexes with neutral macrocyclic ligands containing N 3  donor sets.

zeitschrift für naturforschung b

Synthese und Charakterisierung von 1,3,5-Hexahydrotriazin-Komplexen des Mo o  und Mo VI  / Synthesis and Characterization of 1,3,5-Hexahydrotriazine Complexes of Mo 0  and M o VI