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The compounds Mg 2 Ni 3 P and Mg 2 Ni 3 As were prepared by heating the elements. Their structures have been determined from single-crystal X-ray data. The structure of the phosphide is a rhombohedral ternary variant of the cubic Laves structure type MgCu 2  (R 3̄ m; hexagonal lattice constants: a = 4.971(0) Å, c = 10.961(2) Å). The ordered substitution of one quarter of the metal atoms by phosphorus and the resulting shorter distances are responsible for the rhombohedral symmetry.

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Strukturvarianten des MgCu 2 -Typs: Die Verbindungen Mg 2 Ni 3 P und Mg 2 Ni 3 As / Variants of the MgCu 2  Type: The Compounds Mg 2 Ni 3 P and Mg 2 Ni 3 As