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Cp*TaF 4  (1) (Cp* = η 5 -C 5 Me 5 ) forms a Lewis acid Lewis base adduct with the iminophosphorane HN = PPh 3  (2). The adduct Cp*TaF 4 ·NH=PPh 3  (3) is remarkably stable to thermal decomposition. The X-ray crystal structure of 3 was investigated.

zeitschrift für naturforschung b

Notizen: Darstellung und Struktur des Addukts (η 5 -C 5 Me 5 )TaF 4 · HN =PPh 3  / Preparation and Structure of the Adduct (η 5 -C 5 Me 5 )TaF 4  · HN = PPh 3