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Trialkyl phosphites (2a—c) react with 1,8-naphthosultam (6) to give the respective N-alkylated products 7 a—c. Compounds 7a—c were also prepared by the action of dialkyl phosphites on 6 in the presence of p-TsOH. Moreover, 7 a could be obtained by treating 6 with DMMP (8). On the other hand, chlorinated phosphorus reagents (11) condense with 6 to give products of type 12. Structures of the new products were assigned according to consistent analytical and spectroscopic measurements.

Organophosphorus Chemistry, 18: The Reaction of 1,8-Naphthosultam with Alkyl Phosphites and Chlorinated Phosphorus Reagents