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The crystal structures of Me 2 NSF 2 ⁺ AsF 6 ⁻ (4) and CF 3 SF 2  + AsF 6 ⁻ (6) are reported and the cation structures compared with those of the corresponding isoelectronic neutral phosphanes.

Fluorosulfonium Hexafluoroarsenate RSF 2 + AsF 6 ⁻ / Fluorosulfonium Hexafluoroarsenates, RSF 2 +AsF 6 ⁻