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Cd[AsF 6 ] 2  (1) reacts with cyanogen to yield [Cd{(CN) 2 } 2 SO 2 ][AsF 6 ] 2  (2). 2 crystallizes in the space group Pnma with cell constants a = 1475.2(3); b = 821.7(3); c = 1321.2(9) pm. The coordination sphere of cadmium consists of nine atoms (one oxygen, four fluorines and four nitrogens). Cyanogen forms polymeric links.

zeitschrift für naturforschung b

Über die Reaktion von Dicyan mit Cd(II)-Ionen Röntgenstrukturanalyse von [Cd{(CN) 2 } 2 SO 2  ][AsF 6 ] 2 / The Reaction of Cyanogen with Cd(II) Ions X-Ray Structure Analysis of [Cd{(CN) 2 } 2 SO 2 ][AsF 6 ] 2