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In aminoaerosil, the products of the reaction of γ-aminopropyltriethoxysilane with aerosil. an intraparticular interaction of the basic amino groups with the acidic silanol groups is observed. This behaviour was established a) by adsorption experiments using n-butylamine on aerosil. resp. aminoaerosil of different support density, and b) by microcalorimetric determination of the adsorption energy of acetonitrile using aerosil and aminoaerosils of different support density as substrates.

zeitschrift für naturforschung b

Chemie an starren Grenzflächen, 8. [1] Kinetik der Heterogenumsetzung kovalent über Spacer an Aerosil gebundener Aminogruppen (Aminoaerosil) mit homogen gelösten Isothiocyanaten / Chemistry on Rigid Interfaces, 8 . [1] Kinetics of Suspensions of Aminoaerosil (Aerosil Covalently Linked with 3-Aminopropylgroups) with Isothiocyanates in Homogeneous Solution