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(CO) 4 FeP(R)Cl 2  reacts with Na 2 Cr 2 (CO) 10  to give the μ 3  RP capped trigonal heterom etallic closed cluster Fe(CO) 3 Cr(CO) 4 Cr(CO) 5 (μ 3 -PR)(1) as a major product. ACr(CO) 5 -derivative of a metal substituted phosphane [(μ 2 ( t BuPCl)Fe 2 (CO) 7 )( t BuPH)]Cr(CO) 5  (2) is obtained as a minor component.

Zur Reaktion von (CO) 4 FeP(R)Cl 2 mit Na 2 Cr 2 (CO) 10 / Reactions of (CO) 4 FeP(R)Cl 2 with Na 2 Cr 2 (CO) 10