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Diethyl-hexadecaphosphane (2) and dimethylhexadecaphosphane (3) have been synthesized by reacting dilithium-hexadecaphosphide, Li 2 P 16  (1 ), with ethylbromide and methylbromide, respectively. 2 and 3 are the first polycyclic organophosphanes with  16 P atoms in the molecule.

zeitschrift für naturforschung b

Notizen: Beiträge zur Chemie des Phosphors, 158. Über die Hexadecaphosphane P 16 Et 2  und P 16 Me 2 / Contributions to the Chemistry of Phosphorus, 158. On the Hexadecaphosphanes P 16 Et 2  and P 16 Me 2