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The ethenedithiolato complex [(CO) 3 FeSCH 2 ] 2  (1) is obtained by thermal fragmentation of thiirane-S-oxide in the presence of Fe 3 (CO) 12  in THF and by photolytic reaction of [(CO) 3 FeS] 2  (3) with ethene, respectively. According to an X-ray structure analysis, complex 1 has the same symmetric polyhedron structure as dihydrobenzvalene 2 .

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Synthese und Struktur des Ethendithiolato-Komplexes [(CO) 3 FeSCH 2 ] 2 , einem Dihydrobenzvalen-Analogon/ Synthesis and Structure of the Ethenedithiolato Complex [(CO) 3 FeSCH 2 ] 2 , an Analogon of Dihydrobenzvalene