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1 -Diisopropylamino-3-borolene is readily lithiated by tert-butyllithium in THF to produce lithium (1-diisopropylaminoborolenediide), the second known example of the 6 π-electron borole dianion. Trimethylsilylation of the dianion gives trans-1-diisopropylamino-4,5-bis(trimethylsilyl)-2-borolene. Reaction with [{C 6 (CH 3 ) 6 }RuCl 2 ] 2  affords the (borole)-ruthenium complex [C 6 (CH 3 ) 6 ]Ru[C 4 H 4 BN{CH(CH 3 ) 2 } 2 ].

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Derivate des Borols, IV [1]. Ein Borol-Dianion durch Lithiierung von 1-Diisopropylamino-3-borolen / Derivatives of Borole, IV [1]. A Borole Dianion via Lithiation of 1-Diisopropylamino-3-borolene