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Prussian Blue analogs of the type Fe[M B (CN) 6 ] (M B  = Pd and Pt) crystallize in the face-centered cubic system: space group F m3m -O h  5 , Z = 4. Magnetochemical and Mößbauer spectroscopic measurements have revealed that nitrogen-coordinated iron(II) ions and carbon-coordinated M B (IV) ions are in the high spin state and in the low spin state, respectively, in the temperature range 4.2 to 300 K. Upon the formation of Fe[M B (CN) 6 ] from K 2 [M B (CN) 6 ], the binding energies of N 1s, Pd 3d 5/2  and Pt 4f 7/2  increase while the C 1 s binding energy decreases. This tendency could be interpreted in terms of the inductive effect of iron(II) ions attached to the nitrogen end of cyanide ligands.

zeitschrift für naturforschung b

Mößbauer-und Röntgenphotoelektronen-spektroskopische Untersuchungen an Berlinerblau-Analoga des Typs Fe[M B (CN) 6 ] / Mößbauer and X-Ray Photoelectron Spectroscopic Studies on Prussian Blue Analogs of the Type Fe[M B (CN) 6 ]