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The phosphino and (thio)phosphoryl formamides 1a, b, 2a-c, 3a, b, 4a, b which were partially unknown are synthesized by various methods, and their reactions with carbonylmetal halides of manganese and iron are described. The formation of the P,N- and S,N coordinate chelate complexes, (CO) 4 MnL (5 a, 8a), is limited to the N-phenyl derivatives la and 4a. With L = 2a, b, the unidentate P-coordination predominates. Thus, the carbonylmetal halide complexes cis-(CO) 4 Mn(X)L (6a, b: X = CI, 7a, b: X = Br) and η 5 -C 5 H 5 (CO)Fe(X)L (9a, b: X = I, 10a, b: X = Br) are obtained. Due to the low stability of the formamide complexes, their formation is always accompanied by isocyanate elimination as a side-reaction

zeitschrift für naturforschung b

Phosphinsubstituierte Chelatliganden, IV [1] Neue Diphenylphosphinoformamid-Komplexe des Mangans und Eisens / Phosphine Substituted Chelate Ligands, IV [1] New Diphenylphosphino Formamide Complexes of Manganese and Iron