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S-Perfluoroalkyl-N-pentafluorosulphanyl sulphurmonofluoride imides(Rt - CF 3  (1a) , t-C 3 F 7  (1b)) are prepared by the reaction of NSF 3  with appropriate sulphurtrifluoride derivatives. The fluorine bonded to sulphur(IV) in 1a and 1b is substituted by PCl 5  to give sulphurmonochloride imides(Rt = CF 3  (2a), i-C 3 F 7  (2b)). The chlorine in 2a and 2b can be exchanged by reaction with suitable silver(I) and mercury(II) salts.

Darstellung und Reaktionen von S-Perfluoralkyl-Schwefelmonofluoridimiden / Preparation and Reactions of S-Perfluoroalkyl Sulphurmonofluoride Imides