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The carbamoyl complex [(CO) 4 FeC(O)NMe 2 ][C(NMe 2 ) 3 ] (1) reacts with boron halides of the type BrBR 2  (R = Me, Ph, NMe 2 ) at low temperature to give the boroxycarben complexes 2, which decompose at ambient temperature to the aminoboranes 3 and Fe(CO) 5 . The  1 NMR and IR spectra of the new compounds 2 are reported.

zeitschrift für naturforschung b

Über die Reaktion von [(C0) 4 FeC(O)NMe 2 ] - [C(NMe 2 ) 3 ] +  mit einigen Diorganylbromboranen / On the Reaction of  [(C0) 4 FeC(O)NMe 2 ] - [C(NMe 2 ) 3 ] +  with Some Diorganoboron Bromides