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The new compound CaMnBi 2  has been analytically and structurally characterized. CaMnBi 2  crystallizes in the tetragonal system (a = 450 ± 1 pm, c = 1108 ± 2 pm, space group P4/nmm). Mn and Bi atoms form fourfold pyramids, connected by common edges in the basis to two-dimensional sheets. These sheets are separated by double layers of Ca atoms between which further Bi atoms are located forming squarenets. The structure is strongly related to that of SrZnSb 2  which can be interpreted as a distorted variant of the new CaMnBi 2  type.

Zur Darstellung und Struktur von CaMnBi 2 / On the Preparation and Crystal Structure of CaMnBi 2