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The crystal structure of the monoclinic η5-C 5 H 5 RU(CO) 2 (CONH 2 ) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3 pm, c = 845,2 pm, α= 97,35°, β= 106,11°, and γ= 99,32°). The Ru is pseudo-octahedrally coordinated to the η 5 -C 5 H 5  ring, the two CO groups and the CONH 2  ligand with a planar RuC(O)N-moiety. Dimers are formed by N-H···O hydrogen bonds connecting the carbamoyl ligands of two molecules. Further hydrogen bonds link these dimers to form a helical chain.

Die Kristallstruktur des η 5 -C 5 H 5 Ru(CO) 2 (CONH 2 ) [1] / The Crystal Structure of η 5 -C 5 H 5 Ru(CO) 2 (CONH 2 ) [1]