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N-Cyano-sulfurdifluoride-imide NC-NSF2 and N-cyano-sulfuroxide-difluoride-imide NC-NSOF 2  will react with AsFs to give the N-bonded nitrile adducts F 5 As · NC-NSF 2  (F 5 As · NC-NSOF 2 ). With [M(CO) 5 SO 2 ]+AsF 6 - (M=Mn,Re) the expected complexes [(CO) 5 MNC-NSF 2 ]+AsF 6 -

Fluorhaltige Nitrile als Komplexliganden / Fluorine Containing Nitriles as Complex Ligands