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Reaction of N,N-dialkyl-β-aminoketones (5 and 7) with hydroxylamine hydrochloride in pyridine results in the dealkylated oximine (6). The mechanism of this N-dealkylation may be explained as due to the neighbouring group participation of the oximine formed during the reaction.

An Unusual N-Dealkylation-Neighbouring Group Participations of Oximino Function [1]