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Direct irradiation of each of N-a- and /3-phenethyl toluidine in carbon tetrachloride solution leads t o homolysis of the phenethyl-nitrogen bond forming phenethyl and arylamino free radicals. The fates of such radicals are discussed in terms of the identified products.

Molecular Rearrangements, XV Photolysis and Thermolysis of N- a - and ß-Phenethyl Toluidines