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{(Ru(μ-OCH 3 )(CO) 2 [P(t-C 4 H 9 ) 3 ]} 2  is prepared by the reaction of Ru 3 (CO) 12  with P(t-C 4 H 9 ) 3  in methanol or by refluxing Ru(CO) 3 [P(t-C 4 H 9 ) 3 ] 2  in methanol. The IR, Raman, and NMR spectra are reported and discussed.

Di-μ-methoxi-bis[dicarbonyl(tri-tert-butylphosphin)ruthenium(I)](Ru-Ru)/Di-μ-methoxi-bis[dicarbonyl(tri-tert-butylphosphine)ruthenium(I)](Ru-Ru)