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NaBeAs and NaBeSb crystallize in a modified Ni 2 In-type-structure, space group P 6 3 /mmc–D 6h  4 . Preparation and structure determination with powder and single crystal data are described. The bonds and the structure are discussed in comparison with corresponding compounds of the formula AMe II X. The lattice constants are:

NaBeAs(Sb) – Ternäre Phasen im „aufgefüllten“ NiAs(Ni 2 In)-Typ / NaBeAs(Sb) – Ternary Phases in a „Filled“ NiAs(Ni 2 In)-Structure