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MoS 2 , WS 2  and TiS 2  react with K-naphthalid-solutions to intercalation compounds K x MeS 2 . Na- and Li-naphthalid reduce the sulfides to metal, but in the case of the sodium-compound the first step is intercalation to Na x WS 2 . Li-HMPT-solution reduces MoS 2  to Li x  (HMPT)  n MoS 2  and finally to Mo. The reasons for the differences in the reactive behaviour of the alkali-naphthalid-solutions are discussed.

zeitschrift für naturforschung b

Reaktion von in Schichtengittern kristallisierenden Metalldisulfiden mit Alkali-naphthalid-Lösungen / Reaction of Metalldisulfides Having Layer Structures with Alkalinaphthalides-solutions