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Bi(O 2 PCl 2 ) 3 ·POCl 3 , formed by the reaction of BiCl 3  and Cl 2 O in POCl 3  solution, has been characterised by vibrational spectroscopy. The Bi-atom is surrounded by the O-atoms of the chlorophosphate groups and the POCl 3  in a pseudo-hexahedral arrangement.

zeitschrift für naturforschung b

Darstellung, Eigenschaften und Schwingungsspektrum von Wismut(III)dichlorphosphat, Bi(O 2 PCl 2 ) 3  · OPCl 3  / Preparations, Chemical Properties and the Vibrational Spectra of Bismuthum (III) dichlorphosphate, Bi (O 2 PCl 2 ) 3·OPCl 3