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The reversible one-electron insertion into mono- and 1,4-di-substituted benzene derivatives is favored by dialkoxyboron and especially by dialkylboron groups. The assumption that it should be the symmetric e 2u  benzene molecular orbital which is occupied in the resulting radical anions can be supported by comparison of ESR coupling constants.

Halbstufen-Reduktionspotentiale Bor-substituierter Benzolderivate / Half-Wave Reduction Potentials of Boron Substituted Benzene Derivatives