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It was found that bis- [p- (3-methyl-butyloxy) -phenyl] -thiourea, (applied in the therapy under the name of Thiocarlidum * as a tuberculo- and leprostatic) has two modifications in the solid state. By the aid of thermoanalitical, spectroscopical and X-ray studies it was shown, that the phase transformation arises as a result of the change in the conformtion of the molecule.

Rotational Isomerism in Bis-[p-(3-Methyl-butyloxy)-phenyl]-thiourea