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The potential constants are obtained for the monohaloacetylenes using the general valence force field. The theory of the mean-square amplitude matrices is applied to these molecules and the parallel and perpendicular mean-square amplitudes for the interatomic distances are calculated. The perpendicular amplitudes have been used for calculating the shrinkage effect. The Coriolis coupling coefficients are also obtained for all these molecules.

Potential Constants, Mean Amplitudes of Vibration, Shrinkage Constants and Coriolis Coupling Coefficients of Monohalo Acetylenes