English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The local structures and the spin Hamiltonian parameters (SHPs) for Cu 2+  in (90– x )TeO 2 –10GeO 2 – x WO 3  glasses are theoretically investigated at various WO 3  concentrations ( x =7.5, 15, 22.5 and 30 mol%). Subject to the Jahn-Teller effect, the [CuO 6 ] 10−  groups are found to experience the small or moderate tetragonal elongation distortions (characterised by the relative tetragonal elongation ratios  ρ ≈0.35–3.09%) in C 4  axis. With only three adjusted coefficients  a ,  b  and  ω , the relevant model parameters (Dq,  k  and  ρ ) are described by the Fourier type and linear functions, respectively, and the measured concentration dependences of the d–d transition bands and SHPs are reproduced. The maximum of  g  ∥  and the minimum of | A  ∥ | at  x =15 mol% are illustrated from the abrupt decrease of the copper–oxygen electron cloud admixtures or covalency and the obvious decline of the copper 3d–3s (4s) orbital admixtures due to the decreasing electron cloud density around oxygen ligands spontaneously bonding with Cu 2+  and Te 4+  (W 6+ ), respectively.

Investigations on the Local Structures and the Spin Hamiltonian Parameters for Cu 2+ in (90– x )TeO 2 –10GeO 2 – x WO 3 Glasses