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Some physical properties of ferric chloride-dimethyl sulfone (FeCl 3 -DMSO 2 ) melts were investigated. The phase diagram was determined by differential scanning calorimeter and thermogravimetric analyzer. The electric conductivity, measured with computerized direct-current method, increased with increasing temperature and DMSO 2  content. The conductivity was maximal (0.02149 S/cm) at 115 °C for 30 mol% FeCl 3 . The densities of all melts decreased with increasing temperature and DMSO 2  content. The equivalent conductivities were given by Λ = κM mix /ρ, where M mix  is the mean equivalent weight of the binary melts. These equivalent conductivities were fitted by the equationΛ =Λ o exp(−E Λ  /RT), where the activation energies E Λ  were 8.63, 22.94, 25.92 kJ/mol for 30, 40, 50 mol% FeCl 3 , respectively.

Physical Properties of a New Type of Molten Electrolytes, FeCl 3 -DMSO 2