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The decomposition of tert. butylperoxypivalate dissolved in n-heptane has been measured ir-spectroscopically in optical high-pressure cells up to 2000 bar at temperatures between 65 °C and 105 °C. The reaction follows a first order rate law with an activation energy E a  = 122.3 ±3.0 kJ · mol -1  and an activation volume ⊿V ≠  = 1.6 ± 1.0 cm 3  mol -1  .

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Die Kinetik des Zerfalls von tert. Butylperoxypivalat bei hohen Drücken und Temperaturen / The Kinetics of the Decomposition of tert.Butylperoxypivalate up to High Pressures and Temperatures