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A normal coordinate analysis was performed for some Cl 5 MOPCl 3  molecules (M = Sb, Nb, Ta). The final force field in terms of a described set of symmetry coordinates is reported for Cl 5 SbOPCl 3 . The initial force field for Cl 5 SbOPCl 3  was applied to calculate the vibrational frequencies of the Cl 5 NbOPCl 3  and Cl 5 TaOPCl 3  adducts. An assignment of the vibrational frequencies of the title compounds and the corresponding potential energy distribution terms are given for Cl 5 SbOPCl 3  . For the Cl 5 SbOPCl 3

Normalkoordinatenanalyse und mittlere Schwingungsamplituden für Cl 5 SbOPCl 3 , Cl 5 NbOPCl 3 und Cl 5 TaOPCl 3