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The rotational Zeeman effect in the microwave spectrum of trans- and cis-Thioformic Acid has been investigated at field strengths upto 25.6 kG. Measurements were done for both ⊿M = 0 and ⊿M = ± 1 selection rules for the trans species and for ⊿M = ±1 for the cis species. From the observed splittings the following parameters were obtained for the diagonal elements of the molecular g tensor and the susceptibility anisotropics.

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Molecular g-Values, Magnetic Susceptibility Anisotropics, Second Moments of the Charge Distribution, and Molecular Electric Quadrupole Moments in trans- and cis-Thioformic Acid