English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

Oxidation of cyclohexane is an essential chemical reaction for the industrial manufacture of cyclohexanol and cyclohexanone. These two compounds, together known as ketone–alcohol (KA) oil, are the main feedstock for nylon 6 and nylon 6,6 productions. Several types of catalysts and reaction conditions have been used for cyclohexane oxidation. This paper presents a thorough literature review of catalytic materials used for cyclohexane oxidation to produce KA oil using oxygen, air and other oxidizing agents as well as utilizing different solvents. This review covers research and development reported over the years 2014–2020. This review aims to comprehend the type of catalysts, solvents, oxidants and other reaction parameters used for the oxidation of cyclohexane. Three types of cyclohexane oxidation processes namely thermocatalytic, photocatalytic and microwave-assisted catalytic have been reported. The results of the review showed that metal and metal oxide loaded silica catalysts performed excellently and provided high selectivity of KA oil and cyclohexane conversion. The use of peroxides is not feasible due to their high price compared to air and oxygen. Gold nanoparticles supported on silica performed with high selectivity and good conversion. The use of hydrochloric acid as an additive was found very effective to enhance the photocatalytic oxidation of cyclohexane. Water on the catalyst surface enhanced the reactivity of the photocatalysts since it helps in the generation of hydroxyl radicals.

A comprehensive and updated review of studies on the oxidation of cyclohexane to produce ketone-alcohol (KA) oil