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C 18 H 16 ClN 2 O 2 S·C 7 H 7 O 3 S, monoclinic,  C 2/ c  (no. 15),  a  = 36.911(9) Å,  b  = 9.931(2) Å,  c  = 14.795(3) Å,  β  = 112.32(3)°,  V  = 5017(2) Å 3 ,  Z  = 8,  R    gt   ( F ) = 0.0500,  wR    ref   ( F  2 ) = 0.1447, T = 293 K.

The crystal structure of 5-chloro-6′-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3′-bipyridin]-1′-ium 4-methylbenzenesulfonate