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C 22 H 10 F 4 I 2 N 4 , monoclinic,  P 2 1 / c  (no. 14),  a  = 9.7940(3) Å,  b  = 5.34970(10) Å,  c  = 20.5119(5) Å,  β  = 101.673(3)°,  V  = 1052.49(5) Å 3 ,  Z  = 2,  Rgt   ( F ) = 0.0222, w Rref   ( F   2 ) = 0.0505,  T  = 293(2) K.

Bifurcated halogen bonds in the crystal structure of 2,2′-bi(1,8-naphthyridine)—1,4-diiodotetrafluorobenzene (1/1), C 22 H 10 F 4 I 2 N 4