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C 21 H 25 ClO, orthorhombic,  Pna 2 1  (no. 33),  a  = 14.152(2) Å,  b  = 22.112(3) Å,  c  = 6.0109(7) Å,  V  = 1880.9(4) Å 3 ,  Z  = 4,  R    gt   ( F ) = 0.0586,  wR  ref ( F  2 ) = 0.1227,  T  = 150 K.

Crystal structure of 2,6-di- tert -butyl-4-(4-chlorobenzylidene)cyclohexa-2,5-dien-1-one, C 21 H 25 ClO