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C 12 H 11 ClN 2 O 3 S, monoclinic,  P 2 1 / n  (no. 14),  a  = 4.7305(8) Å,  b  = 21.252(4) Å,  c  = 13.134(2) Å,  β  = 96.286(2)°,  Z  = 4,  V  = 1312.5(4) Å 3 ,  Rgt   ( F ) = 0.1002,  wRref   ( F   2 ) = 0.1118, T = 296 K.

The crystal structure of N ′-(2-chloro-6-hydroxybenzylidene)thiophene-2-carbohydrazide monohydrate, C 12 H 11 ClN 2 O 3 S