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C 10 H 13 N 3 O·C 7 H 6 O 3 , monoclinic,  P 2 1 / n  (no. 14),  a  = 7.4038(9) Å,  b  = 30.448(3) Å,  c  = 7.6744(8) Å,  β  = 112.013(3)°,  V  = 1603.9(3) Å 3 ,  Z  = 4,  Rgt   ( F ) = 0.0492,  wRref   ( F   2 ) = 0.1384, T = 173 K.

The crystal structure of the co-crystal: 2-hydroxybenzoic acid – N ′-(butan-2-ylidene)pyridine-4-carbohydrazide, C 10 H 13 N 3 O·C 7 H 6 O 3